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LITHIUM FLUORIDE LiF
Lithium Fluoride is used for windows, prisms, and lenses in the vacuum UV,
UV, visible and infrared where desired transmission is in the 0.104 µm - 7 µm
range. Modest precautions should be taken against moisture and high energy
radiation damage. LiF is attacked by atmospheric moisture at 400 °C and softens
at 600 °C. LiF is sensitive to thermal shock. Irradiation produces color
centers. The material can be cleaved. VUV grade is available.
Maximum available size: 100 mm Dia x 40 mm Thk.

Main Properties
| Chemical Formula |
LiF |
| Crystal Class |
Cubic |
| Lattice Constant, Å |
4.03 |
| Molecular Weight |
25.94 |
| Density, g/cm3 (20 °C) |
2.60 |
| Reflection Loss, % for two surfaces at 4 µm |
4.4 |
| Dielectric Constant for 102-1010 Hz at 298 K |
9.0 |
| Melting Temperature, K |
1140 |
| Thermal Conductivity, W/(m K) at 314 K |
11.3 |
| Thermal Expansion, 1/K at 300 K |
34.4 x 10-6 |
| Specific Heat, cal/(g K) at 283 K |
0.37 |
| Debye Temperature, K |
732 |
| Bandgap, eV |
13.6 |
| Solubility, g/100 g H2O at 291 K |
0.27 |
| Knoop Hardness, kg/mm2 |
100 |
| Young's Modulus, GPa |
64.77 |
| Apparent Elastic Limit, MPa |
11.2 |
| Shear Modulus, GPa |
55.12 |
| Bulk Modulus, GPa |
62.0 |
| Poisson Ratio |
0.326 |
Refractive Index
| Wavelength, µm |
0.20 |
0.22 |
0.24 |
0.29 |
0.39 |
0.60 |
1.75 |
2.75 |
3.40 |
| Refractive Index |
1.44 |
1.43 |
1.42 |
1.41 |
1.40 |
1.39 |
1.38 |
1.37 |
1.36 |
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